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#Van-der-Waals

~18 min read

A Two-Cell Interface Loses 39% of Its Surface Tension — The Anisotropy of the Korteweg Stress

·6 min read

Across a flat liquid–vapor interface the normal pressure stays constant and only the tangential pressure dips. That dip is surface tension, and a dz=1 lattice loses up to 39% of it.

I Plugged in Pressure Directly and a Still Interface Started to Shiver — Two Forms of Nonideal LBM Forcing

·6 min read

Pressure-form and chemical-potential forcing agree for van der Waals in the continuum, then split on the lattice where the Gibbs-Duhem defect lives.

Where the Ideal Gas Starts to Lie — Compressibility Factor Z and the van der Waals Equation

·6 min read

Nitrogen at 100 bar and 200 K has Z = 0.7905. The ideal-gas density, 168.4 kg/m3, is about 26 percent lighter than the real 213.0.